跳转到内容

1-溴-1-甲基环己烷

维基百科,自由的百科全书
1-溴-1-甲基环己烷
识别
CAS号 931-77-1  checkY
PubChem 12502129
SMILES
 
  • BrC1(C)CCCCC1
性质
化学式 C7H13Br
摩尔质量 177.08 g·mol−1
沸点 42 °C(15 mmHg)
79 °C(38 mmHg)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

1-溴-1-甲基环己烷是一种有机化合物,化学式为C7H13Br,它是溴甲基环己烷同分异构体之一。

合成

1-溴-1-甲基环己烷可由1-甲基环己烯氢溴酸反应得到,吸附剂使用硅胶[2]它也可由甲基环己烷在紫外线照射下反应得到。[3]

参考文献

  1. ^ G. F. Dvorko, I. V. Koshchii, E. A. Ponomareva. Kinetics and mechanism of unimolecular heterolysis of cage-like compounds: XIX. Effect of the nucleofuge nature on the activation parameters of heterolysis of 1-halo-1-methylcyclohexanes in cyclohexane. Heterolysis rate ratio in aprotic and protic solvents. Russian Journal of Organic Chemistry. 2007-01, 43 (1): 50–55 [2023-02-17]. ISSN 1070-4280. doi:10.1134/S1070428007010046 (英语). 
  2. ^ Kiyoshi Tanemura. Silica gel-mediated hydrohalogenation of unactivated alkenes using hydrohalogenic acids under organic solvent-free conditions. Tetrahedron Letters. 2018-12, 59 (49): 4293–4298 [2023-02-17]. doi:10.1016/j.tetlet.2018.10.043. (原始内容存档于2022-10-23) (英语). 
  3. ^ Manabe, Yoshiyuki; Kitawaki, Yuriko; Nagasaki, Masahiro; Fukase, Koichi; Matsubara, Hiroshi; Hino, Yoshiko; Fukuyama, Takahide; Ryu, Ilhyong. Revisiting the Bromination of C-H Bonds with Molecular Bromine by Using a Photo-Microflow System. Chemistry - A European Journal (Wiley). 2014-08-29, 20 (40): 12750–12753. ISSN 0947-6539. doi:10.1002/chem.201402303.