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2-甲基十一烷

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2-甲基十一烷
英文名 2-Methylundecane.png
识别
CAS号 7045-71-8  checkY
SMILES
 
  • CCCCCCCCCC(C)C
性质
化学式 C12H26
摩尔质量 170.33 g·mol−1
沸点 208.9 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

2-甲基十一烷是一种烷烃,化学式为C12H26。它可由壬基溴化锌維基數據所列Q822864922-溴丙烷双(1,5-环辛二烯)镍和双取代噁唑基吡啶的催化下反应制得;[2]1-(5-羟甲基-2-呋喃基)-5-甲基-1-己烯-3-酮在三氟甲磺酸铕催化下氢化,也能得到2-甲基十一烷。[3]它存在于番石榴沉香等植物的叶中。[4][5]

参考文献

  1. ^ Mukwembi, S., Nyabadza, F. A new model for predicting boiling points of alkanes. Sci Rep 11, 24261 (2021). doi:10.1038/s41598-021-03541-z.
  2. ^ Paul A. Wender, Thomas E. Smith, Hung A. Duong, Janis Louie, Eric A. Standley, Sarah Z. Tasker. Bis(1,5-cyclooctadiene)nickel(0). Encyclopedia of Reagents for Organic Synthesis, 2015. doi:10.1002/047084289X.rb118.pub3.
  3. ^ Juha Keskiväli , Pauli Wrigstedt , Kalle Lagerblom , Timo Repo. One-step Pd/C and Eu(OTf)3 catalyzed hydrodeoxygenation of branched C11 and C12 biomass-based furans to the corresponding alkanes. Applied Catalysis A: General, 2017. 534. doi:10.1016/j.apcata.2017.01.017.
  4. ^ Shaza H. Aly; et al. Chemical Constituents, Antioxidant, and Enzyme Inhibitory Activities Supported by In-Silico Study of n-Hexane Extract and Essential Oil of Guava Leaves. Molecules 2022, 27(24), 8979. doi:10.3390/molecules27248979.
  5. ^ Ridwanti Batubara; et al. Rasayan J. Chem., 14(2), 751-759 (2021). doi:10.31788/ RJC.2021.1426021.

延伸阅读

  • Yury V. Kissin (1990). Relative reactivities of alkanes in catalytic cracking reactions. Journal of Catalysis, 126(2), 600–609. doi:10.1016/0021-9517(90)90023-d
  • Yury V. Kissin (1994). Degenerate Non-primary Products in Catalytic Cracking of Isoalkanes. Journal of Catalysis, 146(2), 358–369.doi:10.1006/jcat.1994.1074