三氟甲磺酸锰

三氟甲磺酸锰
识别
CAS号	55120-76-8（无水） ; 1301749-91-6（六水）
性质
化学式	C2F6MnO6S2
摩尔质量	353.08 g·mol−1
外观	白色吸湿性粉末（无水）; 白色粉末（六水）
熔点	> 400 °C（无水）; 86 °C（六水）
溶解性（水）	可溶于乙腈，微溶于乙醇，难溶于丙酮和乙醚
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三氟甲磺酸锰是一种无机化合物，化学式为Mn(CF₃SO₃)₂。它可由锰和无水三氟甲磺酸在氩气保护下于乙腈中反应制得，或通过碳酸锰和三氟甲磺酸在水中反应得到。^[1]它的乙醇溶液与1,4-二(1-咪唑基)苯（bib）的二氯甲烷溶液扩散结晶，可以得到{[Mn(bib)₂(CF₃SO₃)₂](CH₂Cl₂)₄}_n。^[3]

参考文献

^ ^1.0 ^1.1 ^1.2 ^1.3 Miao, Cheng-Xia; Sun, Wei, Manganese Bis(trifluoromethanesulfonate), Chichester, UK: John Wiley & Sons, Ltd, 2012-03-15, doi:10.1002/047084289x.rn01455
^ ^2.0 ^2.1 Sniekers, Jeroen; Malaquias, João C.; Van Meervelt, Luc; Fransaer, Jan; Binnemans, Koen. Manganese-containing ionic liquids: synthesis, crystal structures and electrodeposition of manganese films and nanoparticles. Dalton Transactions (Royal Society of Chemistry (RSC)). 2017, 46 (8): 2497–2509. ISSN 1477-9226. doi:10.1039/c6dt04781e.
^ Ye, Gan; Zou, Kang-Yu; Yang, Ying; Wang, Jun-Jie; Gou, Xiao-Feng; Li, Zuo-Xi. Anion effect on the topological frameworks of a series of manganese coordination polymers based on 1,4-bis(imidazol-1-yl)-benzene: Syntheses, crystal structures and magnetic properties. Journal of Solid State Chemistry (Elsevier BV). 2015, 225: 31–40. ISSN 0022-4596. doi:10.1016/j.jssc.2014.11.015.

拓展阅读

Amelia M. Wheaton, Jill A. Chipman, Michael D. Roy, and John. F. Berry. Metal–Metal Bond Umpolung in Heterometallic Extended Metal Atom Chains. Inorg. Chem. 2022, 61, 38, 15058–15069. doi:10.1021/acs.inorgchem.2c02118.

[reagent-1] 1.0 ^1.1 ^1.2 ^1.3 Miao, Cheng-Xia; Sun, Wei, Manganese Bis(trifluoromethanesulfonate), Chichester, UK: John Wiley & Sons, Ltd, 2012-03-15, doi:10.1002/047084289x.rn01455

[sniekers-2] 2.0 ^2.1 Sniekers, Jeroen; Malaquias, João C.; Van Meervelt, Luc; Fransaer, Jan; Binnemans, Koen. Manganese-containing ionic liquids: synthesis, crystal structures and electrodeposition of manganese films and nanoparticles. Dalton Transactions (Royal Society of Chemistry (RSC)). 2017, 46 (8): 2497–2509. ISSN 1477-9226. doi:10.1039/c6dt04781e.

[3] Ye, Gan; Zou, Kang-Yu; Yang, Ying; Wang, Jun-Jie; Gou, Xiao-Feng; Li, Zuo-Xi. Anion effect on the topological frameworks of a series of manganese coordination polymers based on 1,4-bis(imidazol-1-yl)-benzene: Syntheses, crystal structures and magnetic properties. Journal of Solid State Chemistry (Elsevier BV). 2015, 225: 31–40. ISSN 0022-4596. doi:10.1016/j.jssc.2014.11.015.

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