5α-胆甾烷-3β-醇甲酸酯
| 5α-胆甾烷-3β-醇甲酸酯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 10437-24-8 
|
| 性质 | |
| 化学式 | C28H48O2 |
| 摩尔质量 | 416.68 g·mol−1 |
| 熔点 | 117 °C（390 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
5α-胆甾烷-3β-醇甲酸酯是一种有机化合物，化学式为C28H48O2。它可由5α-胆甾烷-3β-醇和二甲基甲酰胺反应得到；[2]在二(三甲基硅基)氨基钾的催化下，甲酸甲酯也可作为甲酰化试剂进行反应。[3]它可以被硼氢化钠-三氟化硼还原为3-甲氧基-5α-胆甾烷。[4]
参考文献
- ^ Goswami, Papori; Hazarika, Saroj; Borah, Parinita; Chowdhury, Pritish. Chloro- or bromo-trimethylsilane induced rapid and quantitative acid-ester conversion for steroid based alcohols with various carboxylic acids under solvent free conditions. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 2003. 42B (3): 678-682.
- ^ Z. Arnold. Synthetic reactions of dimethylformamide. IX. Synthesis of esters of formic acid. Collection of Czechoslovak Chemical Communications. 1961, 26 (6): 1723–1726 [2021-11-20]. ISSN 0010-0765. doi:10.1135/cccc19611723. （原始内容存档于2022-02-24） （英语）.
- ^ Jared Fernando, Alison Levens, Daniel Moock, David Lupton. N-Heterocyclic Carbene Catalyzed Transformylation. Synthesis. 2017-08, 49 (15): 3505–3510 [2021-11-20]. ISSN 0039-7881. doi:10.1055/s-0036-1588449. （原始内容存档于2018-06-03） （英语）.
- ^ George Pettit, Usha Ghatak, Brian Green, T Kasturi, David Piatak. Communications- Steroids and Related Natural Products. IV. Reduction of Lactones to Cyclic Ethers.. The Journal of Organic Chemistry. 1961-05, 26 (5): 1685–1686 [2021-11-20]. ISSN 0022-3263. doi:10.1021/jo01064a644 （英语）.