三炔丙胺
| 三炔丙胺 | |
|---|---|
| |
| 英文名 | Tripropargylamine Tri(prop-2-yn-1-yl)amine |
| 识别 | |
| CAS号 | 6921-29-5 
|
| 性质 | |
| 化学式 | C9H9N |
| 摩尔质量 | 131.17 g·mol−1 |
| 密度 | 0.922 g·cm−3[1] |
| 沸点 | 82 °C（355 K）（15 Torr）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
三炔丙胺是一种有机化合物，化学式为C9H9N。它可由3-溴-1-丙炔和氨水反应得到。[3]它和烷基叠氮化物反应，得到含1H-1,2,3-三唑环的叔胺衍生物。[4]它和稀盐酸反应，生成三炔丙胺盐酸盐。[5]
参考文献
- ^ Chauvelier, Janine; Gaudemar, Marcel. Propargylamines. Compt. rend., 1951. 232: 167-169.
- ^ Kostyanovskii, R. G.; Bystrov, V. M.; Samoilova, Z. E.; Chervin, I. I. Hindered interaction of an electron pair of Group V elements. III. Dipropargylamine nitrogen（俄文）. Doklady Akademii Nauk SSSR, 1969. 188 (1): 137-140. ISSN: 0002-3264.
- ^ Gragert, Maria; Schunack, Marlen; Binder, Wolfgang H. Azide/Alkyne-“Click”-Reactions of Encapsulated Reagents: Toward Self-Healing Materials. Macromolecular Rapid Communications. 2011, 32 (5): 419–425. ISSN 1022-1336. doi:10.1002/marc.201000687.
- ^ Topchiy, Maxim A.; Ageshina, Alexandra A.; Chesnokov, Gleb A.; Sterligov, Grigorii K.; Rzhevskiy, Sergey A.; Gribanov, Pavel S.; Osipov, Sergey N.; Nechaev, Mikhail S.; Asachenko, Andrey F. Alkynyl‐ or Azido‐Functionalized 1,2,3‐Triazoles: Selective MonoCuAAC Promoted by Physical Factors. ChemistrySelect. 2019, 4 (25): 7470–7475. ISSN 2365-6549. doi:10.1002/slct.201902135.
- ^ Steiner, T.; Schreurs, A. M. M.; Kroon, J. Tris(prop-2-ynyl)ammonium chloride. Acta Crystallographica Section C Crystal Structure Communications. 1999, 55 (7): 1156–1158. ISSN 0108-2701. doi:10.1107/S0108270199003509.