跳转到内容

乙酰丙酮铂(II)

维基百科,自由的百科全书
乙酰丙酮铂(II)
别名 乙酰丙酮合铂(II)
乙酰丙酮亚铂
二(2,4-戊二酮)合铂
识别
CAS号 15170-57-7  checkY
PubChem 10960186
SMILES
 
  • CC(=O)C=C(C)[O-]. CC(=O)C=C(C)[O-].[Pt+2]
性质
化学式 C10H14O4Pt
摩尔质量 393.3 g·mol−1
外观 黄色固体
密度 2.362 g/cm3
熔点 239.4 °C(512.5 K)(分解)[1]
溶解性 难溶
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

乙酰丙酮铂(II)是一种配位化合物,化学式为Pt(O2C5H7)2

制备

在1 N高氯酸介质中,将高氯酸汞加入至四氯合铂(II)酸钾溶液中搅拌,再加入高氯酸银,过滤后得到含有橙黄色的[Pt(H2O)4]2+离子,在碱性条件下将乙酰丙酮的碱性溶液加至上述Pt(II)溶液中,产生暗灰色沉淀,搅动下变为黄色,即乙酰丙酮铂(II)。[2]

[Pt(H2O)4]2+ + 2 H(acac) + 2 OH → Pt(acac)2 + 6 H2O

它也可由六氟合铂(IV)酸在含有乙醇的高氯酸中与乙酰丙酮反应得到。[3]

性质

乙酰丙酮铂(II)可以和其它配位能力更强的配体反应,得到新的配合物。[4][5]它和乙酰丙酮银混合,可以增加乙酰丙酮银的热稳定性。[6]

参考文献

  1. ^ Flanagan, Scott; Hall, Eric; Bowie, Wade; Fuhs, James W.; Logan, Robbie; Maniei, Farzaneh; Hunt, Andrew. A design-of-experiments approach to modeling activity coefficients in solvent mixtures: a case study using platinum(ii) acetylacetonate in mixtures of acetone, cyclohexanol, 1,2,3,4-tetrahydronaphthalene and propylene carbonate. Green Chemistry. 2005, 7 (5): 333. ISSN 1463-9262. doi:10.1039/b418130a. 
  2. ^ Okeya, Seichi; Kawaguchi, Shinichi; Kuhlmann, Erven; Orchin, Milton. The bis(β-Diketonato)Platinum(II) Complexes: 65–69. 2007. ISSN 1934-4716. doi:10.1002/9780470132517.ch20. 
  3. ^ Zharkova, G. I.; Igumenov, I. K.; Tkachev, S. V.; Zemskov, S. V. Platinum(II) β-diketonates(俄文). Koordinatsionnaya Khimiya, 1982. 8 (1): 74-81. ISSN: 0132-344X.
  4. ^ Allefeld, Nadine; Kurscheid, Boris; Neumann, Beate; Stammler, Hans-Georg; Ignat'ev, Nikolai; Hoge, Berthold. Coordination Properties of Perfluoroethyl- and Perfluorophenyl-Substituted Phosphonous acids, RfP(OH)2. Chemistry - A European Journal. 2015, 21 (39): 13666–13675. ISSN 0947-6539. doi:10.1002/chem.201501984. 
  5. ^ Kimura, Takeshi; Watanabe, Shuichi; Sawada, Shin-ichi; Shibasaki, Yuji; Oishi, Yoshiyuki. Preparation and optical properties of polyimide films linked with porphyrinato Pd (II) and Pt (II) complexes through a triazine ring and application toward oxygen sensors. Journal of Polymer Science Part A: Polymer Chemistry. 2017, 55 (6): 1086–1094. ISSN 0887-624X. doi:10.1002/pola.28469. 
  6. ^ Křenek, T.; Kovářík, T.; Pola, M.; Jakubec, I.; Bezdička, P.; Bastl, Z.; Pokorná, D.; Urbanová, M.; Galíková, A.; Pola, J. Enhancement of thermal stability of silver(I) acetylacetonate by platinum(II) acetylacetonate. Thermochimica Acta. 2013, 554: 1–7. ISSN 0040-6031. doi:10.1016/j.tca.2012.12.001. 

拓展阅读