二乙基乙酰胺

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二乙基乙酰胺
识别
CAS号 685-91-6  checkY
性质
化学式 C6H13NO
摩尔质量 115.17 g·mol⁻¹
密度 0.9130 g·cm−3[1]
熔点 <20 °C[2]
沸点 185.5 °C[2]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

二乙基乙酰胺是一种有机化合物,化学式为C6H13NO。它可由二乙胺乙酸酐[3]N-乙酰氧基丁二酰亚胺[4]反应制得。在催化剂的存在下,它可以被氢气还原为三乙胺[5]

参考文献

  1. ^ Kormer, M. V.; Tolchinskii, S. E.; Maretina, I. A. Vinylacetylenic ynamines as dehydrating reagents. Zhurnal Organicheskoi Khimii, 1983. 19 (6): 1166-1170. ISSN: 0514-7492.
  2. ^ 2.0 2.1 "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2021-05-17].
  3. ^ Gangadhar Meshram, Vishvanath D. Patil. Simple and Efficient Method for Acetylation of Alcohols, Phenols, Amines, and Thiols Using Anhydrous NiCl 2 Under Solvent-Free Conditions. Synthetic Communications. 2009-11-18, 39 (24): 4384–4395 [2021-05-17]. ISSN 0039-7911. doi:10.1080/00397910902906529 (英语). 
  4. ^ Hong Li, Zi-Bo Pang, Zhi-Feng Jiao, Fei Lin. Synthesis and Application of a Microgel-Supported Acylating Reagent by Coupled Ring-Opening Metathesis Polymerization and Activators Re-Generated by Electron Transfer for Atom Transfer Radical Polymerization. Journal of Combinatorial Chemistry. 2010-03-08, 12 (2): 255–259 [2021-05-17]. ISSN 1520-4766. doi:10.1021/cc900162w (英语). 
  5. ^ Mario Stein, Bernhard Breit. Catalytic Hydrogenation of Amides to Amines under Mild Conditions. Angewandte Chemie International Edition. 2013-02-18, 52 (8): 2231–2234 [2021-05-17]. doi:10.1002/anie.201207803 (英语).