环辛炔
环辛炔 | |
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识别 | |
CAS号 | 1781-78-8 ![]() |
性质 | |
化学式 | C8H12 |
摩尔质量 | 108.18 g·mol−1 |
沸点 | 80 °C(60 torr)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
环辛炔是一种有机化合物,化学式为C8H12。它可以1-溴环辛烯和二异丙氨基钠反应制得。[2]它和1-叠氮基金刚烷在乙腈中反应,可以得到1-金刚烷基-1H-环辛烷并三唑。[3]它可以和卤化亚铜形成配合物(C8H12)2Cu2X2(X=Cl, Br, I)。[4]
参考文献
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- ^ Yun Ma, Russell F. Algera, David B. Collum. Sodium Diisopropylamide in N,N -Dimethylethylamine: Reactivity, Selectivity, and Synthetic Utility. The Journal of Organic Chemistry. 2016-11-18, 81 (22): 11312–11315 [2022-04-06]. ISSN 0022-3263. PMC 5242189
. PMID 27768310. doi:10.1021/acs.joc.6b02287. (原始内容存档于2022-04-06) (英语).
- ^ Matthias Müller, Cäcilia Maichle-Mössmer, Holger F. Bettinger. Boryl Azides in 1,3-Dipolar Cycloadditions. The Journal of Organic Chemistry. 2014-06-20, 79 (12): 5478–5483 [2022-04-06]. ISSN 0022-3263. doi:10.1021/jo500549m (英语).
- ^ Gunther Gröger, Ulrich Behrens, Falk Olbrich. Monomeric and Dimeric Cyclooctyne-Stabilized Complexes of Copper(I) 1. Organometallics. 2000-08-01, 19 (17): 3354–3360 [2022-04-06]. ISSN 0276-7333. doi:10.1021/om000079g. (原始内容存档于2022-04-06) (英语).