環十三烷
環十三烷 | |
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IUPAC名 Cyclotridecane | |
识别 | |
CAS号 | 295-02-3 ![]() |
PubChem | 136145 |
ChemSpider | 119922 |
SMILES |
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InChI |
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InChIKey | UEVXKGPJXXDGCX-UHFFFAOYAD |
性质 | |
化学式 | C13H26 |
摩尔质量 | 182.35 g·mol−1 |
熔点 | 23.5 °C(297 K) |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
環十三烷(Cyclotridecane)是13個碳的环烷烃,化學式為。它可以环十二酮和氰乙酸乙酯为原料经多步反应制得;[1]它也可以双环戊酮环己酮三过氧化物为原料反应得到。[2]
參考資料
- ^ Matthias K. Diedrich; Frank-Gerrit Klärner. The Effect of Pressure on Cyclizations. The Ring-Size Dependent Reaction Volumes of the Cyclization of 1-Alkenes to Cycloalkanes. Experimental Measurement of Activation and Reaction Volumes of the Intramolecular Diels−Alder Reaction of 1,3,8-Nonatriene and 1,3,9-Decatriene. Temperature Dependence of Activation and Reaction Volumes. J. Am. Chem. Soc. 1998, 120, 25, 6212–6218. doi:10.1021/ja973936p.
- ^ Alexandra Seemann; Johannes Panten; Andreas Kirschning. Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties. J. Org. Chem. 2021, 86, 20, 13924–13933. doi:10.1021/acs.joc.1c00663