碳化十五羰基五钌

碳化十五羰基五钌
别名	μ5-碳化十五羰基五钌
识别
CAS号	51205-07-3
性质
化学式	C16O15Ru5
摩尔质量	937.52 g·mol−1
外观	红色晶体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

碳化十五羰基五钌是一种有机钌化合物（英语：Organoruthenium chemistry），化学式为Ru₅C(CO)₁₅。它可由Ru₆C(CO)₁₇和一氧化碳在70 °C、80 atm反应制得。它可作为电子对的接受体参与反应，如和一分子或二分子乙腈形成加合物；和碘反应得到Ru₅C(CO)₁₅I₂；和三苯基膦反应得到Ru₅C(CO)₁₅PPh₃。^[2]它在庚烷中加压、加热分解，得到Ru₆C(CO)₁₇。^[1]它可以活化甲酰基的C-H键。^[3]

参考文献

^ ^1.0 ^1.1 Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, José Puga, Paul R. Raithby, Maria J. Rosales, Mary McPartlin, William Clegg. The synthesis of [Ru 5 C(CO) 15 ] by the carbonylation of [Ru 6 C(CO) 17 ] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru 5 C(CO) 15 ], [Ru 5 C(CO) 15 (MeCN)], [Ru 5 C(CO) 14 (PPh 3 )], [Ru 5 C(CO) 13 (PPh 3 ) 2 ], and [Ru 5 (µ-H) 2 C(CO) 12 {Ph 2 P(CH 2 ) 2 PPh 2 }]. J. Chem. Soc., Dalton Trans. 1983, (2): 277–290 [2020-12-08]. ISSN 0300-9246. doi:10.1039/DT9830000277 （英语）.
^ David H. Farrar, Peter F. Jackson, Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, Mary McPartlin. A high-yield synthesis of Ru5C(CO)15 by the carbonylation of Ru6C(CO)17; the X-ray structure analyses of Ru5C(CO)15 and Ru5C(CO)14PPh3. Journal of the Chemical Society, Chemical Communications. 1981, (9): 415 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39810000415 （英语）.
^ Richard D. Adams, Humaiara Akter, Jonathan D. Tedder. CH activations in aldehydes in reactions with Ru5(μ5-C)(CO)15. Journal of Organometallic Chemistry. 2018-09, 871: 159–166 [2020-12-08]. doi:10.1016/j.jorganchem.2018.07.017. （原始内容存档于2020-02-16）（英语）.

[Johnson-1] 1.0 ^1.1 Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, José Puga, Paul R. Raithby, Maria J. Rosales, Mary McPartlin, William Clegg. The synthesis of [Ru 5 C(CO) 15 ] by the carbonylation of [Ru 6 C(CO) 17 ] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru 5 C(CO) 15 ], [Ru 5 C(CO) 15 (MeCN)], [Ru 5 C(CO) 14 (PPh 3 )], [Ru 5 C(CO) 13 (PPh 3 ) 2 ], and [Ru 5 (µ-H) 2 C(CO) 12 {Ph 2 P(CH 2 ) 2 PPh 2 }]. J. Chem. Soc., Dalton Trans. 1983, (2): 277–290 [2020-12-08]. ISSN 0300-9246. doi:10.1039/DT9830000277 （英语）.

[2] David H. Farrar, Peter F. Jackson, Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, Mary McPartlin. A high-yield synthesis of Ru5C(CO)15 by the carbonylation of Ru6C(CO)17; the X-ray structure analyses of Ru5C(CO)15 and Ru5C(CO)14PPh3. Journal of the Chemical Society, Chemical Communications. 1981, (9): 415 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39810000415 （英语）.

[3] Richard D. Adams, Humaiara Akter, Jonathan D. Tedder. CH activations in aldehydes in reactions with Ru5(μ5-C)(CO)15. Journal of Organometallic Chemistry. 2018-09, 871: 159–166 [2020-12-08]. doi:10.1016/j.jorganchem.2018.07.017. （原始内容存档于2020-02-16）（英语）.

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