碳化十五羰基五锇是一种有机锇化合物，化学式为Os5C(CO)15，它与Fe5C(CO)15同构（但不同晶）。[1]它可在十八羰基六锇的热分解反应中产生。[2]它在回流条件下可以和醇（ROH）反应，生成HOs5C(CO)14(CO2R)。[3]
参考文献
- ^ 1.0 1.1 Peter F. Jackson, Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls, Mary McPartlin, William J. H. Nelson. Synthesis of the carbido anion [Os5C(CO)15I]? and the X-ray crystal structures of Os5C(CO)15 and [(Ph3P)2N][Os5C(CO)15I]. Journal of the Chemical Society, Chemical Communications. 1980, (12): 564 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39800000564 （英语）.
- ^ C.R. Eady, B.F.G. Johnson, J. Lewis, T. Matheson. The preparation of Ru5C(CO)15 and Os5C(CO)15. Journal of Organometallic Chemistry. 1973-09, 57 (2): C82–C83 [2020-12-08]. doi:10.1016/S0022-328X(00)86593-6. （原始内容存档于2018-06-12） （英语）.
- ^ Dario Braga, Brian F. G. Johnson, Jack Lewis, Mary McPartlin, William J. H. Nelson, J. Nichola Nicholls, Maria D. Vargas. Activation of a carbonyl group in the pentanuclear carbido clusters Os5C(CO)15 and I2Os5C(CO)15 by alcohols: X-ray analysis of HOs5C(CO)14(CO2Et) and IOs5C(CO)14(CO2Me). Journal of the Chemical Society, Chemical Communications. 1982, (16): 966 [2020-12-08]. ISSN 0022-4936. doi:10.1039/c39820000966 （英语）.
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