2,2'-二吡啶胺
2,2'-二吡啶胺 | |
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IUPAC名 N-pyridin-2-ylpyridin-2-amine | |
别名 | 2,2'-iminodipyridine |
识别 | |
CAS号 | 1202-34-2 ![]() |
PubChem | 14547 |
ChemSpider | 13888 |
SMILES |
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性质 | |
化学式 | C10H9N3 |
摩尔质量 | 171.2 g·mol−1 |
外观 | 白色固体 |
熔点 | 90.5 °C(364 K) |
沸点 | 307.5 °C(581 K) |
危险性 | |
GHS危险性符号![]() | |
GHS提示词 | Warning |
H-术语 | H315, H319, H335 |
P-术语 | P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
2,2'-二吡啶胺是一种有机化合物,化学式为(C5H4N)2NH。它可由吡啶和氨基钠加热反应得到,或由2-氨基吡啶与2-氯吡啶在氧化钡上共热制得。[1]它是一种配体,可以形成配合物。[2]其共轭碱和金属的盐(2,2'-二吡啶氨基化物)是已知的。[3]
参考文献
- ^ Brogden, David W.; Berry, John F. Coordination Chemistry of 2,2’-Dipyridylamine: The Gift That Keeps on Giving. Comments on Inorganic Chemistry. 4 September 2015, 36 (1): 17–37. doi:10.1080/02603594.2015.1079522.
- ^ Wang, Suning. Luminescence and electroluminescence of Al(III), B(III), Be(II) and Zn(II) complexes with nitrogen donors. Coordination Chemistry Reviews. 2001, 215: 79–98. doi:10.1016/S0010-8545(00)00403-3.
- ^ Cotton, F. Albert; Daniels, Lee M.; Jordan; Murillo, Carlos A. Symmetrical and Unsymmetrical Compounds Having a Linear Co36+ Chain Ligated by a Spiral Set of Dipyridyl Anions. Journal of the American Chemical Society. 1997, 119 (43): 10377–10381. doi:10.1021/JA971997H.