2-硝基乙醇
| 2-硝基乙醇 | |
|---|---|
| |
| 别名 | β-硝基乙醇 |
| 识别 | |
| CAS号 | 625-48-9 
|
| 性质 | |
| 化学式 | C2H5NO3 |
| 摩尔质量 | 91.07 g·mol−1 |
| 密度 | 1.296 g·cm−3[1] |
| 熔点 | −80 °C[2] |
| 沸点 | 102 °C（11 Torr）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
2-硝基乙醇是一种有机化合物，化学式为NO2CH2CH2OH。它可由硝基甲烷和甲醛在碱性条件下反应制得。[3]其它制备方法还有2-碘乙醇和亚硝酸银的反应[4]及环氧乙烷和亚硝酸钠的反应[5]。它和乙酰氯反应，可以得到乙酸-2-硝基乙酯。[6]
参考文献
- ^ 1.0 1.1 Norman Levy, Charles W. Scaife, Arthur E. Wilder Smith. 241. Addition of dinitrogen tetroxide to olefins. Part II. Ethylene. Journal of the Chemical Society (Resumed). 1946: 1096 [2020-06-28]. ISSN 0368-1769. doi:10.1039/jr9460001096 （英语）.
- ^ "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2020-06-28].
- ^ Madhu Sudan Manna, Santanu Mukherjee. Organocatalytic Enantioselective Formal C(sp 2 )–H Alkylation. Journal of the American Chemical Society. 2015-01-14, 137 (1): 130–133 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja5117556 （英语）.
- ^ Wayland E. Noland, Philip J. Hartman. The Nitroethylation of Indole. A New Synthesis of Tryptamine. Journal of the American Chemical Society. 1954-06, 76 (12): 3227–3228 [2020-06-28]. ISSN 0002-7863. doi:10.1021/ja01641a044 （英语）.
- ^ Jagat C. Borah, Siddhartha Gogoi, Joshodeep Boruwa, Nabin C. Barua. LaCl 3 · 7H 2 O‐Promoted Regioselective Ring Opening of Epoxides Using NaNO 2 in Ether–Water System: A Facile Synthesis of 2‐Nitroalcohols. Synthetic Communications. 2005-03, 35 (6): 873–878 [2020-06-28]. ISSN 0039-7911. doi:10.1081/SCC-200051043 （英语）.
- ^ Colin Philip Leslie. The stereochemistry of the SE2 reaction of pentadienylsilanes [Dissertation], 1994. Department of Chemistry, University of Cambridge. 1630067.