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Sar配体

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Sar配体
IUPAC名
3,6,10,13,16,19-Hexazabicyclo[6.6.6]icosane
别名 3,6,10,13,16,19-六氮杂双环[6.6.6]二十烷
识别
CAS号 64189-50-0  checkY
PubChem 6394006
ChemSpider 4908238
SMILES
 
  • C1CNCC2CNCCNCC(CN1)CNCCNC2
InChI
 
  • 1S/C14H32N6/c1-2-16-8-14-11-19-5-3-17-9-13(7-15-1)10-18-4-6-20-12-14/h13-20H,1-12H2
InChIKey NVOVSXGZALWAFS-UHFFFAOYSA-N
性质
化学式 C14H32N6
摩尔质量 284.44 g·mol−1
密度 0.911±0.06 g·cm−3[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

Sar3,6,10,13,16,19-六氮杂双环[6.6.6]二十烷)是一种有机化合物,化学式为C14H32N6。它可由三氯化三(乙二胺)合钴(III)硝基甲烷甲醛在碱性条件下反应,得到配位钴(III)的硝基配体,经还原、氯化、二次还原、配体取代(CN取代sar)后将其萃取得到。[2]它可以和金属形成螯合物[3]

参考文献

  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-09-25].
  2. ^ Ga Bottomley, Ij Clark, Ii Creaser, Lm Engelhardt, Rj Geue, Ks Hagen, Jm Harrowfield, Ga Lawrance, Pa Lay, Am Sargeson, Aj See, Bw Skelton, Ah White, Fr Wilner. The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines. Australian Journal of Chemistry. 1994, 47 (1): 143 [2021-09-25]. ISSN 0004-9425. doi:10.1071/CH9940143 (英语). 
  3. ^ J. Mroziński, A. Skorupa, A. Pochaba, Y. Dromzée, M. Verdaguer, E. Goovaerts, H. Varcammen, B. Korybut-Daszkiewicz. Sarcophagine Ni(II) diperchlorate: synthesis, crystallographic structure, magnetism and high-field EPR. Journal of Molecular Structure. 2001-01, 559 (1-3): 107–118 [2021-09-25]. doi:10.1016/S0022-2860(00)00696-7. (原始内容存档于2020-02-11) (英语).