Sar配体
Sar配体 | |
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IUPAC名 3,6,10,13,16,19-Hexazabicyclo[6.6.6]icosane | |
别名 | 3,6,10,13,16,19-六氮杂双环[6.6.6]二十烷 |
识别 | |
CAS号 | 64189-50-0 ![]() |
PubChem | 6394006 |
ChemSpider | 4908238 |
SMILES |
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InChI |
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InChIKey | NVOVSXGZALWAFS-UHFFFAOYSA-N |
性质 | |
化学式 | C14H32N6 |
摩尔质量 | 284.44 g·mol−1 |
密度 | 0.911±0.06 g·cm−3[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
Sar(3,6,10,13,16,19-六氮杂双环[6.6.6]二十烷)是一种有机化合物,化学式为C14H32N6。它可由三氯化三(乙二胺)合钴(III)、硝基甲烷和甲醛在碱性条件下反应,得到配位钴(III)的硝基配体,经还原、氯化、二次还原、配体取代(CN−取代sar)后将其萃取得到。[2]它可以和金属形成螯合物。[3]
参考文献
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFinder. [2021-09-25].
- ^ Ga Bottomley, Ij Clark, Ii Creaser, Lm Engelhardt, Rj Geue, Ks Hagen, Jm Harrowfield, Ga Lawrance, Pa Lay, Am Sargeson, Aj See, Bw Skelton, Ah White, Fr Wilner. The Synthesis and Structure of Encapsulating Ligands: Properties of Bicyclic Hexamines. Australian Journal of Chemistry. 1994, 47 (1): 143 [2021-09-25]. ISSN 0004-9425. doi:10.1071/CH9940143 (英语).
- ^ J. Mroziński, A. Skorupa, A. Pochaba, Y. Dromzée, M. Verdaguer, E. Goovaerts, H. Varcammen, B. Korybut-Daszkiewicz. Sarcophagine Ni(II) diperchlorate: synthesis, crystallographic structure, magnetism and high-field EPR. Journal of Molecular Structure. 2001-01, 559 (1-3): 107–118 [2021-09-25]. doi:10.1016/S0022-2860(00)00696-7. (原始内容存档于2020-02-11) (英语).