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马拉普拉德反应

维基百科,自由的百科全书

Malaprade反应(Malaprade reaction)是邻二醇在温和条件下被高碘酸高碘酸盐氧化得,产生二醇裂解英语Glycol cleavage反应。[1][2]这个反应是由Léon Malaprade法语Léon Malaprade首次报告的[3]

用于糖化学中结构的鉴定。

参见

参考资料

  1. ^ 406. Malaprade Reaction (Malaprade Oxidation). Comprehensive Organic Name Reactions and Reagents. Wiley. 2010: 1807–1810. doi:10.1002/9780470638859.conrr406. 
  2. ^ H. O. House, Modern Synthetic Reactions (W. A. Benjamin, Menlo Park, California, 2nd ed., 1972) pp 353-359; K. W. Bentley in Elucidation of Organic Structures by Physical and Chemical Methods Pt. 2, K. W. Bentley, G. W. Kirby, Eds. (Wiley, New York, 2nd ed., 1973) pp 177-185.
  3. ^ L. Malaprade, Bull. Soc. Chim. Fr. [4] 43, 683 (1928); Compt. Rend. 186, 382 (1928).