4,4'-偶氮吡啶
| 4,4'-偶氮吡啶 | |
|---|---|
| |
| 识别 | |
| CAS号 | 2632-99-7 
|
| 性质 | |
| 化学式 | C10H8N4 |
| 摩尔质量 | 184.2 g·mol−1 |
| 外观 | 橙色针状晶体 |
| 熔点 | 107—108 °C（380—381 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
4,4'-偶氮吡啶是一种有机化合物，化学式为C10H8N4。它可由4-氨基吡啶和10%次氯酸钠溶液反应制得，[1]或由1,2-二(4-吡啶基)肼和氧气在DMF中于80 °C反应得到。[2]它和氰化镍在甲苯中回流反应，可以得到四氰合镍(II)酸(4,4'-偶氮吡啶)合镍(II)。[3]它和五羰基氯化铼在四氢呋喃/甲苯中回流反应，可以得到三羰基(4,4'-偶氮吡啶)氯化铼四聚体。[4]
参考文献
- ^ 1.0 1.1 Jean Pierre Launay, Myriam Tourrel-Pagis, Jean Francois Lipskier, Valerie Marvaud, Christian Joachim. Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system. Inorganic Chemistry. 1991-03, 30 (5): 1033–1038 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic00005a029. （原始内容存档于2022-11-07） （英语）.
- ^ Yu Lin, Hao Wu, Ziang Liu, Jin Li, Rui Cai, Makoto Hashimoto, Lei Wang. Additive-free aerobic oxidation of hydroazobenzenes: Access to azobenzenes and epoxidation of enones. Tetrahedron Letters. 2022-10, 108: 154132 [2022-11-07]. doi:10.1016/j.tetlet.2022.154132 （英语）.
- ^ Jeffrey T. Culp, Catherine Madden, Kristi Kauffman, Fan Shi, Christopher Matranga. Screening Hofmann Compounds as CO 2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates. Inorganic Chemistry. 2013-04-15, 52 (8): 4205–4216 [2022-11-07]. ISSN 0020-1669. doi:10.1021/ic301893p. （原始内容存档于2022-11-07） （英语）.
- ^ Shih-Sheng Sun, Alistair J. Lees. Self-Assembly Triangular and Square Rhenium(I) Tricarbonyl Complexes: A Comprehensive Study of Their Preparation, Electrochemistry, Photophysics, Photochemistry, and Host−Guest Properties. Journal of the American Chemical Society. 2000-09-01, 122 (37): 8956–8967 [2022-11-07]. ISSN 0002-7863. doi:10.1021/ja001677p. （原始内容存档于2022-11-07） （英语）.