羊茅麥角鹼
羊茅麥角鹼 | |
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IUPAC名 6,8β-Dimethylergoline | |
系統名 (6aR,9R,10aR)-7,9-Dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[4,3-fg]quinoline | |
別名 | 狐茅麥角鹼 |
識別 | |
CAS號 | 569-26-6 ![]() |
PubChem | 332915 |
ChemSpider | 294963 |
SMILES |
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性質 | |
化學式 | C16H20N2 |
摩爾質量 | 240.34 g·mol−1 |
外觀 | 白色固體[1] |
熔點 | 236—240 °C(509—513 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
羊茅麥角鹼((8β,10β)-6,8-二甲基麥角靈)是一種有機化合物,化學式為C16H20N2,它是一種麥角靈真菌分離物。[2]它可以2-溴-3-硝基苄溴為原料經多步反應、柱分離製得。[1]
參考文獻
- ^ 1.0 1.1 1.2 Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing. Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi-Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine. Organic Letters (American Chemical Society (ACS)). 2017-06-08, 19 (12): 3323–3326. ISSN 1523-7060. doi:10.1021/acs.orglett.7b01504.
- ^ Wallwey, C; Matuschek, M; Xie, XL; Li, SM. Ergot alkaloid biosynthesis in Aspergillus fumigatus: Conversion of chanoclavine-I aldehyde to festuclavine by the festuclavine synthase FgaFS in the presence of the old yellow enzyme FgaOx3. Organic & Biomolecular Chemistry. 2010, 8 (15): 3500–8. PMID 20526482. doi:10.1039/c003823g.