鉬酸釹

鉬酸釹
識別
CAS號	13477-90-2
性質
化學式	Nd2(MoO4)3
外觀	藍色固體
溶解性（水）	難溶
	若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

鉬酸釹是一種無機化合物，化學式為Nd₂(MoO₄)₃。它可由氧化釹和三氧化鉬在高溫反應得到。^[2]或通過硝酸釹和(NH₄)₆Mo₇O₂₄反應，再將得到的沉澱高溫處理製得。^[1]它和鉬酸鈉在高溫反應可以得到NaNd(MoO₄)₂。^[3]它在350~700 °C和硫化氫反應，生成硫化釹和二硫化鉬。^[4]在780~870 K，它可以被氫氣還原為Nd₂Mo₃O₉。^[5]

參考文獻

^ ^1.0 ^1.1 Q Huang, J Xu, W Li. Preparation of tetragonal defect scheelite-type RE2(MoO4)3 (RE=La TO Ho) by precipitation method. Solid State Ionics. 1989-02, 32–33: 244–249 [2022-05-17]. doi:10.1016/0167-2738(89)90228-2. （原始內容存檔於2022-06-18）（英語）.
^ Rode, E. Ya.; Lysanova, G. V.; Kuznetsov, V. G.; Gokhman, L. Z. Synthesis and physicochemical study of rare earth molybdates. Zhurnal Neorganicheskoi Khimii, 1968. 13 (5): 1295-1302. ISSN 0044-457X.
^ Mokhosoev, M. V.; Get'man, E. I.; Kokot, I. F. Double sodium-neodymium molybdates. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1969. 5 (6): 1107-1112. ISSN 0002-337X.
^ Yampol'skaya, V. V.; Serebrennikov, V. V. Interaction of rare earth molybdates with hydrogen sulfide at elevated temperatures. Tr. Tomsk. Univ., 1973. 240: 86-89. CAN80: 140751.
^ Gopalakrishnan, Jagannatha; Manthiram, Araumugam. Topochemically controlled hydrogen reduction of scheelite-related rare earth metal molybdates. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981. 3: 668-672.

[QH-1] 1.0 ^1.1 Q Huang, J Xu, W Li. Preparation of tetragonal defect scheelite-type RE2(MoO4)3 (RE=La TO Ho) by precipitation method. Solid State Ionics. 1989-02, 32–33: 244–249 [2022-05-17]. doi:10.1016/0167-2738(89)90228-2. （原始內容存檔於2022-06-18）（英語）.

[2] Rode, E. Ya.; Lysanova, G. V.; Kuznetsov, V. G.; Gokhman, L. Z. Synthesis and physicochemical study of rare earth molybdates. Zhurnal Neorganicheskoi Khimii, 1968. 13 (5): 1295-1302. ISSN 0044-457X.

[3] Mokhosoev, M. V.; Get'man, E. I.; Kokot, I. F. Double sodium-neodymium molybdates. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1969. 5 (6): 1107-1112. ISSN 0002-337X.

[4] Yampol'skaya, V. V.; Serebrennikov, V. V. Interaction of rare earth molybdates with hydrogen sulfide at elevated temperatures. Tr. Tomsk. Univ., 1973. 240: 86-89. CAN80: 140751.

[5] Gopalakrishnan, Jagannatha; Manthiram, Araumugam. Topochemically controlled hydrogen reduction of scheelite-related rare earth metal molybdates. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981. 3: 668-672.

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