跳至內容

1-硝基萘

維基百科,自由的百科全書
1-硝基萘
別名 α-硝基萘
識別
CAS號 86-57-7  checkY
PubChem 6849
ChemSpider 6588
SMILES
 
  • C1=CC=C2C(=C1)C=CC=C2[N+](=O)[O-]
Beilstein 1867714
UN編號 2538
EINECS 201-684-5
ChEBI 34104
KEGG C14040
性質
化學式 C10H7NO2
摩爾質量 173.17 g·mol−1
外觀 淺黃色固體
密度 1.332 g·cm−3[1]
熔點 59 °C(332 K)[2]
溶解性 0.0035 g(25 °C)[3]
危險性
GHS危險性符號
《全球化學品統一分類和標籤制度》(簡稱「GHS」)中易燃物的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中有毒物質的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中有害物質的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中對人體有害物質的標籤圖案《全球化學品統一分類和標籤制度》(簡稱「GHS」)中對環境有害物質的標籤圖案
GHS提示詞 危險
H-術語 H228, H301, H315, H319, H335, H351, H411
P-術語 P201, P202, P210, P240, P241, P261, P264, P270, P271, P273, P280, P281, P301+310, P302+352
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

1-硝基萘是一種有機化合物,化學式為C10H7NO2。它可由的硝化反應製備,混酸是最常見的硝化試劑,[4][5]也有文獻報道使用硝酸鉍[6]二氧化氮[7]N-硝基糖精[8]等進行硝化反應。它可以被還原劑(如氫氣[9]硼氫化鈉[10]水合肼[11]等)還原為1-萘胺

參考文獻

  1. ^ "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2020-12-28].
  2. ^ Badgujar, D. M.; Talwar, M. B.; Asthana, S. N.; Mahulikar, P. P. Environmentally benign synthesis of aromatic nitro compounds using silica supported inorganic nitrates. Journal of Scientific & Industrial Research, 2007. 66 (3): 250-251. ISSN: 0022-4456.
  3. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-12-28].
  4. ^ Khabarov, Yu. G.; Veshnyakov, V. A.; Snigirev, I. A. Method for producing 1-nitronaphthalene. 2018. RU 2669774 C1.
  5. ^ Gerald Booth. Wiley-VCH Verlag GmbH & Co. KGaA , 編. Naphthalene Derivatives. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. 2000-06-15 [2020-12-28]. ISBN 9783527306732. doi:10.1002/14356007.a17_009 (英語). 
  6. ^ Susanta Samajdar, Frederick F Becker, Bimal K Banik. Surface-mediated highly efficient regioselective nitration of aromatic compounds by bismuth nitrate. Tetrahedron Letters. 2000-10, 41 (42): 8017–8020 [2020-12-28]. doi:10.1016/S0040-4039(00)01397-6. (原始內容存檔於2018-06-27) (英語). 
  7. ^ Kuiyi You, Zhongcang Zhou, Jian Jian, Renjie Deng, Pingle Liu, Qiuhong Ai, He’an Luo. A simple approach for preparation of dinitronaphthalene compounds from the nitration reaction of 1-nitronaphthalene with NO2 as nitration reagent. Research on Chemical Intermediates. 2015-11, 41 (11): 8307–8315 [2020-12-28]. ISSN 0922-6168. doi:10.1007/s11164-014-1893-1 (英語). 
  8. ^ Roxan Calvo, Kun Zhang, Alessandro Passera, Dmitry Katayev. Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin. Nature Communications. 2019-12, 10 (1) [2020-12-28]. ISSN 2041-1723. PMC 6667458可免費查閱. PMID 31363083. doi:10.1038/s41467-019-11419-y. (原始內容存檔於2019-11-15) (英語). 
  9. ^ Huan Fu, Luna Ruan, Jianhua Liao, An Pei, Jun Liu, Li Zeng, Kai Yang, Lihua Zhu, Bing Hui Chen. PtNi/C bimetallic nanocatalyst with high catalytic performance and stability for 1-nitronaphthalene hydorgenation to 1-naphthylamine. Molecular Catalysis. 2020-10, 494: 111151 [2020-12-28]. doi:10.1016/j.mcat.2020.111151 (英語). 
  10. ^ Haydar Göksu, Nursefa Zengin, Hakan Burhan, Kemal Cellat, Fatih Şen. A Novel Hydrogenation of Nitroarene Compounds with Multi Wall Carbon Nanotube Supported Palladium/Copper Nanoparticles (PdCu@MWCNT NPs) in Aqueous Medium. Scientific Reports. 2020-12, 10 (1) [2020-12-28]. ISSN 2045-2322. PMC 7229225可免費查閱. PMID 32415148. doi:10.1038/s41598-020-64988-0. (原始內容存檔於2021-10-02) (英語). 
  11. ^ Upendra Sharma, Praveen Kumar Verma, Neeraj Kumar, Vishal Kumar, Manju Bala, Bikram Singh. Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst. Chemistry - A European Journal. 2011-05-16, 17 (21): 5903–5907 [2020-12-28]. doi:10.1002/chem.201003621 (英語).