十二氫聯苯烯
十二氫聯苯烯 | |
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識別 | |
CAS號 | 53485-49-7 ![]() 29782-49-8(rel-(4aR,4bR,8aS,8bS)) ![]() 51319-08-5(rel-(4aR,4bS,8aS,8bS)) ![]() 51319-07-4(rel-(4aR,4bR,8aR,8bR)) ![]() 29782-48-7(rel-(4aR,4bS,8aR,8bS)) ![]() 939-02-6(rel-(4aR,4bS,8aS,8bR)) ![]() |
SMILES |
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性質 | |
化學式 | C12H20 |
摩爾質量 | 164.29 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
十二氫聯苯烯是一種有機化合物,化學式為C12H20。它可由環己烯在三氟甲磺酸亞銅的光催化下二聚得到[1],也可由環己烯和環己烯酮經光化學環加成、多步還原反應製得。[2]
參考文獻
- ^ Robert G. Salomon; Kirsten Folting; William E. Streib; Jay K. Kochi. Copper(I) catalysis in photocycloadditions. II. Cyclopentene, cyclohexene, and cycloheptene. J. Am. Chem. Soc. 1974, 96, 4, 1145–1152. doi:10.1021/ja00811a031.
- ^ Phyllis A. Leber; et al. Thermal isomerizations of cis,anti,cis-tricyclo[6.4.0.02,7]dodec-3-ene to trans- and cis,endo-tricyclo[6.2.2.02,7]dodec-9-ene: diradical conformations and stereochemical outcomes in [1,3] carbon shifts. Tetrahedron, 2007. 63 (27). doi:10.1016/j.tet.2007.02.088.