碳酸-3-氯丙烯酯
| 碳酸-3-氯丙烯酯 | |
|---|---|
| |
| 別名 | 3-氯丙烯環碳酸酯 |
| 識別 | |
| CAS號 | 2463-45-8 
|
| 性質 | |
| 化學式 | C4H5ClO3 |
| 摩爾質量 | 136.53 g·mol−1 |
| 熔點 | ＜−40 °C[1] |
| 沸點 | 104—107 °C（377—380 K）（0.1 mmHg）[2] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
碳酸-3-氯丙烯酯是一種有機化合物，化學式為C4H5ClO3。它可由環氧氯丙烷和二氧化碳在叔胺存在下於100~130 °C、50~70 atm反應得到，[1]但在催化劑存在下，反應在相對溫和的條件下進行。[3]它和金屬鈉在甲苯中反應，可以得到1,2,5,6-己四醇二碳酸酯。[4]它和乙二胺在氧化鎂催化下於乙醇中加熱反應，可以得到2-咪唑烷酮。[5]
參考文獻
- ^ 1.0 1.1 Grishchenko, N. F.; Pokorskii, V. N.; Yablochkina, M. N. Chloropropylene carbonate, a new selective solvent for aromatic hydrocarbons（俄文）. Vestn. Tekhn. i Ekon. Inform. Nauchn.-Issled. Inst. Tekhn.-Ekon. Issled. Gos. Kom. Khim. i Neft. Prom. pri Gosplane SSSR, 1963. 10: 44.
- ^ Tadatomi Nishikubo, Takashi Iizawa, Makoto Iida, Naoki Isobe. Convenient syntheses of cyclic carbonates by new reaction of oxiranes with β-butyrolactone. Tetrahedron Letters. 1986-01, 27 (32): 3741–3744 [2023-03-11]. doi:10.1016/S0040-4039(00)83868-X （英語）.
- ^ Jessica Honores, Diego Quezada, Gustavo Chacón, Oriol Martínez-Ferraté, Mauricio Isaacs. Synthesis of Cyclic Carbonates from CO2 and Epoxide Catalyzed by Co, Ni and Cu Complexes in Ionic Liquids. Catalysis Letters. 2019-07, 149 (7): 1825–1832 [2023-03-11]. ISSN 1011-372X. doi:10.1007/s10562-019-02728-4 （英語）.
- ^ National Technical University 「Kharkiv Polytechnic Institute」 21, Frunze str., 61002 Kharkiv, Ukraine, Arnold Karateev, Denis Litvinov, National Technical University 「Kharkiv Polytechnic Institute」 21, Frunze str., 61002 Kharkiv, Ukraine, Olesya Kalkamanova, National Technical University 「Kharkiv Polytechnic Institute」 21, Frunze str., 61002 Kharkiv, Ukraine. Nonisocyanate” Polyhydroxy Urethanes Based on the Raw Material of a Plant Origin. Chemistry & Chemical Technology. 2014-09-01, 8 (3): 329–338 [2023-03-11]. doi:10.23939/chcht08.03.329. （原始內容存檔於2023-03-11）.
- ^ Sachin R. Jagtap, Yogesh P. Patil, Shin-Ichiro Fujita, Masahiko Arai, Bhalchandra M. Bhanage. Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines. Applied Catalysis A: General. 2008-06, 341 (1-2): 133–138 [2023-03-11]. doi:10.1016/j.apcata.2008.02.035. （原始內容存檔於2022-11-27） （英語）.
拓展閱讀
- Angela Dibenedetto, Antonella Angelini, Michele Aresta, Jayashree Ethiraj, Carlo Fragale, Francesco Nocito. Converting wastes into added value products: from glycerol to glycerol carbonate, glycidol and epichlorohydrin using environmentally friendly synthetic routes. Tetrahedron. 2011-02, 67 (6): 1308–1313 [2023-03-11]. doi:10.1016/j.tet.2010.11.070. （原始內容存檔於2023-05-20） （英語）.