苯并[a]芴
苯並[a]芴[1] | |
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IUPAC名 11H-Benzo[a]fluorene | |
別名 | 1,2-苯並芴 |
識別 | |
CAS號 | 238-84-6 ![]() |
PubChem | 9195 |
ChemSpider | 8840 |
SMILES |
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InChI |
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InChIKey | HKMTVMBEALTRRR-UHFFFAOYAQ |
EINECS | 205-944-9 |
RTECS | DF6382000 |
KEGG | C19343 |
性質 | |
化學式 | C17H12 |
莫耳質量 | 216.277 g·mol⁻¹ |
外觀 | 白色固體[2] |
密度 | 0.819 g/cm3 |
熔點 | 189.5 °C(463 K) |
沸點 | 405 °C(678 K) |
溶解性(水) | 0.000045 g/L |
溶解性 | 可溶於乙醚、苯、氯仿 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
苯並[a]芴是一種稠環芳香烴,化學式為C17H12,它是苯並芴的同分異構體之一。它可以二苯乙炔和1-溴萘(或1-氯萘)為原料合成得到。[2]它和正丁基鋰反應後,再與三甲基氯矽烷反應,可以得到11-三甲基矽基-11H-苯並[a]芴。[3]
參考文獻
- ^ Lide, David R., Handbook of Chemistry and Physics 87, Boca Raton, Florida: CRC Press: 3–42, 8–119, 1998, ISBN 0-8493-0594-2
- ^ 2.0 2.1 Lee, Che-Wei; Liu, En-Chih; Wu, Yao-Ting. Palladium-Catalyzed Reaction of Haloarenes with Diarylethynes: Synthesis, Structural Analysis, and Properties of Methylene-Bridged Arenes. The Journal of Organic Chemistry (American Chemical Society (ACS)). 2015-10-09, 80 (21): 10446–10456. ISSN 0022-3263. doi:10.1021/acs.joc.5b02111.
- ^ Kawanishi, Kazuyoshi; Yoshida, Tomoyasu; Aoyama, Yoshinori. Polymer compound for light emitting device with excellent luminance life. 2019. JP2019163455.