三氯乙酸铒

三氯乙酸铒
英文名	erbium trichloroacetate
别名	三氯醋酸铒
识别
CAS号	97186-94-2
性质
化学式	Er(CCl3COO)3
摩尔质量	654.402 g·mol⁻¹
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三氯乙酸铒是镧系元素铒的三氯乙酸盐，化学式为Er(CCl₃COO)₃，可以形成三斜晶系的二水合物。^[1]^[2]它可溶于水，其水溶液不稳定。^[3]它可由氢氧化铒和三氯乙酸在≤18 °C时反应得到。它可以和4,4'-联吡啶形成配合物。^[4]三氯乙酸铒的固体加热分解，生成无水氯化铒。^[5]

参考文献

^ Antsyshkina, A.S.; Poraj-Koshits, M.A.; Ostrikova, V.N. Kristallicheskaya struktura trikhloratsetata ehrbiya Er(CCl₃COO)₃·2H₂O（俄文）. Zhurnal Neorganicheskoj Khimii, 1988. 20 (6).
^ Takashi Imai, Akira Ouchi. The Structure of μ-Aquabis(μ-trichloroacetato)bis[aquabis(trichloroacetato)erbium(III)] Hydrate, [{Er(CCl 3 CO 2 ) 2 (H 2 O)} 2 (CCl 3 CO 2 ) 2 (H 2 O)] n · n H 2 O. Bulletin of the Chemical Society of Japan. 1987-01, 60 (1): 408–410 [2020-01-18]. ISSN 0009-2673. doi:10.1246/bcsj.60.408 （英语）.
^ 无机化学丛书第七卷钪稀土元素. 科学出版社. pp 227-228.
^ A. Czylkowska. New complexes of heavy lanthanides with 4,4′-bipyridine and trichloroacetates: Synthesis, thermal and other properties. Journal of Thermal Analysis and Calorimetry. 2012-12, 110 (3): 1299–1308 [2020-01-18]. ISSN 1388-6150. doi:10.1007/s10973-011-2041-4 （英语）.
^ B. S. Mathur, T. R. Bhat. Studies on rare earth trichloroacetates. I. Thermal Behaviour in Air and in Nitrogen Atmosphere. Zeitschrift für anorganische und allgemeine Chemie. 1966-03, 343 (3-4): 220–224 [2020-01-18]. ISSN 0044-2313. doi:10.1002/zaac.19663430315 （德语）.

[1] Antsyshkina, A.S.; Poraj-Koshits, M.A.; Ostrikova, V.N. Kristallicheskaya struktura trikhloratsetata ehrbiya Er(CCl₃COO)₃·2H₂O（俄文）. Zhurnal Neorganicheskoj Khimii, 1988. 20 (6).

[2] Takashi Imai, Akira Ouchi. The Structure of μ-Aquabis(μ-trichloroacetato)bis[aquabis(trichloroacetato)erbium(III)] Hydrate, [{Er(CCl 3 CO 2 ) 2 (H 2 O)} 2 (CCl 3 CO 2 ) 2 (H 2 O)] n · n H 2 O. Bulletin of the Chemical Society of Japan. 1987-01, 60 (1): 408–410 [2020-01-18]. ISSN 0009-2673. doi:10.1246/bcsj.60.408 （英语）.

[3] 无机化学丛书第七卷钪稀土元素. 科学出版社. pp 227-228.

[4] A. Czylkowska. New complexes of heavy lanthanides with 4,4′-bipyridine and trichloroacetates: Synthesis, thermal and other properties. Journal of Thermal Analysis and Calorimetry. 2012-12, 110 (3): 1299–1308 [2020-01-18]. ISSN 1388-6150. doi:10.1007/s10973-011-2041-4 （英语）.

[5] B. S. Mathur, T. R. Bhat. Studies on rare earth trichloroacetates. I. Thermal Behaviour in Air and in Nitrogen Atmosphere. Zeitschrift für anorganische und allgemeine Chemie. 1966-03, 343 (3-4): 220–224 [2020-01-18]. ISSN 0044-2313. doi:10.1002/zaac.19663430315 （德语）.

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