β-生育酚 (英语:β-Tocopherol )是四种生育酚 之一,分子式C28 H48 O2 ,是构成维生素E 的化合物 之一[ 2] [ 3] 。在氯化镁 、三乙胺 存在下,它和甲醛 反应,得到羟基邻位甲酰化的产物;[ 4] 它和四丁基三溴化铵 反应,得到羟基邻位溴化的产物;[ 5] 和溴 -氢氧化钠 反应时,则发生氧化-卤化和重排反应。[ 6]
参考文献
^ "Drugs - Synonyms and Properties" data were obtained from Ashgate Publishing Co. (US). 2000. ISBN 0-566-08228-4 . Retrieved from SciFinder. [2021-11-21].
^ Food and Agriculture Organization ; World Health Organization . 9. Vitamin E . Joint FAO/WHO Expert Consultation on Human Vitamin and Mineral Requirements (报告). Bangkok, Thailand: FAO Rome. 2001 [2021-11-20 ] . (原始内容存档 于2022-04-01).
^ Burton, G. W.; Ingold, K. U. Autoxidation of biological molecules. 1. Antioxidant activity of vitamin E and related chain-breaking phenolic antioxidants in vitro. Journal of the American Chemical Society. 1981, 103 (21): 6472–6477. doi:10.1021/ja00411a035 .
^ Khaled Alsabil, Guillaume Viault, Sorphon Suor-Cherer, Jean-Jacques Helesbeux, Joumaa Merza, Vincent Dumontet, Luis Manuel Peña-Rodriguez, Pascal Richomme, Denis Séraphin. Efficient ortho-formylation in vitamin E series, application to the semi-synthesis of natural 5- and 7-formyl-δ-tocotrienols revealing an unprecedented 5-bromo-7-formyl exchange . Tetrahedron. 2017-12, 73 (49): 6863–6870 [2021-11-20 ] . doi:10.1016/j.tet.2017.10.039 . (原始内容存档 于2018-06-15) (英语) .
^ Jia-fei Poon, Vijay P. Singh, Jiajie Yan, Lars Engman. Regenerable Antioxidants-Introduction of Chalcogen Substituents into Tocopherols . Chemistry - A European Journal. 2015-02-02, 21 (6): 2447–2457 [2021-11-20 ] . doi:10.1002/chem.201405895 (英语) .
^ Stefan Böhmdorfer, Anjan Patel, Andreas Hofinger, Thomas Netscher, Lars Gille, Thomas Rosenau. Bromination of Tocopherols: Oxidative Halogenations and Rearrangements . European Journal of Organic Chemistry. 2011-06, 2011 (16): 3036–3049 [2021-11-20 ] . doi:10.1002/ejoc.201100153 (英语) .
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