六氟砷酸镁 是一种无机化合物 ,化学式为Mg(AsF6 )2 。它可由氟化镁 和五氟化砷 在无水氟化氢 中于室温反应得到。[ 1] [ 2] 它可以和稀有气体氟化物反应,生成[Mg(XeF2 )(XeF4 )](AsF6 )2 [ 3] 、[Mg(KrF2 )4 ](AsF6 )2 [ 4] 等。它受热分解,生成氟化镁。[ 5]
参考文献
^ Frlec, B.; Gantar, D.; Holloway, J. H. New metal(II) hexafluoroarsenates: preparation and some properties. Vestnik Slovenskega Kemijskega Drustva , 1979. 26 (4): 415-420. ISSN: 0560-3110.
^ B. Frlec, D. Gantar, J.H. Holloway. Metal (II) hexafluoroarsenates: Preparation and vibrational spectroscopy of MF2·2AsF5 (M = Mg, Ca, Sr, Ba, Mn, Co, Ni, Cd, Hg, Pb) adducts [1] . Journal of Fluorine Chemistry. 1982-01, 19 (3-6): 485–500 [2020-05-29 ] . doi:10.1016/S0022-1139(00)83148-6 . (原始内容存档 于2018-06-20) (英语) .
^ Gašper Tavčar, Boris Žemva. XeF 4 as a Ligand for a Metal Ion . Angewandte Chemie International Edition. 2009-02-09, 48 (8): 1432–1434 [2020-05-29 ] . ISSN 1433-7851 . doi:10.1002/anie.200803365 (英语) .
^ Matic Lozinšek, Hélène P. A. Mercier, David S. Brock, Boris Žemva, Gary J. Schrobilgen. Coordination of KrF 2 to a Naked Metal Cation, Mg 2+ . Angewandte Chemie International Edition. 2017-05-22, 56 (22): 6251–6254 [2020-05-29 ] . doi:10.1002/anie.201611534 (英语) .
^ Boris Frlec, Darja Gantar, John H. Holloway. Metal (II) hexafluoroarsenates: Thermal decomposition studies on the adducts MF2·2AsF5 (M = Mg, Ca, Sr, Mn, Co, Ni, Cd, Hg, Pb), 2MF2·3AsF5 (M = Fe, Cu, Zn) and MF2·AsF5 (M = Ag, Sn) . Journal of Fluorine Chemistry. 1982-04, 20 (2): 217–226 [2020-05-29 ] . doi:10.1016/S0022-1139(00)82210-1 . (原始内容存档 于2018-06-25) (英语) .