疊氮化鉍是一種無機化合物,化學式為Bi(N3)3,對撞擊和摩擦敏感[1]。它最早由Thomas M. Klapötke和Axel Schulz於1997年通過碘化鉍和疊氮化銀在乙腈中的反應製得並由紅外表徵,產物無法和同時生成的碘化銀分離。[4]2010年,Alexander Villinger和Axel Schulz通過三氟化鉍和三甲基疊氮矽烷的反應製得了純淨的疊氮化鉍。[3]它的多種溶劑合物是已知的。[1]
參考文獻
^ 1.01.11.2Rosenstengel, Kati; Schulz, Axel; Villinger, Alexander. Solid State Structure of Bi(N3)3, Bi(N3)3·Solvates and the Structural Dynamics in the [Bi(N3)6]3– Anion. Inorganic Chemistry (American Chemical Society (ACS)). 2013-05-09, 52 (10): 6110–6126. ISSN 0020-1669. doi:10.1021/ic400493v.
^Haiges, Ralf; Rahm, Martin; Dixon, David A.; Garner, Edward B.; Christe, Karl O. Binary Group 15 Polyazides. Structural Characterization of [Bi(N3)4]−, [Bi(N3)5]2–, [bipy·Bi(N3)5]2–, [Bi(N3)6]3–, bipy·As(N3)3, bipy·Sb(N3)3, and [(bipy)2·Bi(N3)3]2 and on the Lone Pair Activation of Valence Electrons. Inorganic Chemistry (American Chemical Society (ACS)). 2011-12-23, 51 (2): 1127–1141. ISSN 0020-1669. doi:10.1021/ic202307a.
^Klapötke, Thomas M.; Schulz, Axel. GROUP 15 TRIAZIDES: A COMPREHENSIVE THEORETICAL STUDY AND THE PREPARATION OF BISMUTH TRIAZIDE. Main Group Metal Chemistry (Walter de Gruyter GmbH). 1997, 20 (5). ISSN 2191-0219. doi:10.1515/mgmc.1997.20.5.325.